WebJun 23, 2024 · Chemodivergent transformations of amides using gem-diborylalkanes as pro-nucleophiles - Nature Communications. Amides are versatile synthetic … WebSep 6, 2024 · Here, a catalyst-controlled chemodivergent 1,6-addition of p-quinone methides with alkynes was developed, affording diverse alkynyl- and vinyl-substituted diarymethanes. In this transformation, copper catalyzed the direct 1,6-addition of p-QMs with alkynes, while iron promoted the three components reaction of p-QMs, alkynes, and …
Chemodivergent coupling of azoarenes with benzyl alcohols via a ...
WebAbstract: Chemodivergent cross-couplings are those in which either one of two (or more) potentially reactive functional groups can be made to react based on choice of conditions. In particular, this review focuses on cross-couplings involving two different (pseudo)halides that can compete for the role of the electrophilic coupling partner. The WebOct 25, 2024 · Abstract. A palladium-catalyzed oxidative tandem process of enallenols was accomplished within a homogeneous/heterogeneous catalysis manifold, … nursing infinity scarf pattern
Iridium‐Catalyzed Enantioselective and Chemodivergent Allenylic ...
WebJan 13, 2024 · Abstract. Establishing chemodivergent synthetic strategies remains a daunting task in the realm of free-radical reaction manifolds. In the December issue of Chem, Glorius and co-workers resolve ... WebMar 30, 2024 · Palladium-catalyzed, solvent-dependent intramolecular oxypalladation-triggered domino sequences of internal alkynes bearing tethered nucleophilic carboxylic ester and electrophilic enone functionalities were developed for the chemodivergent synthesis of two completely distinct biologically significant complex molecules including … WebJun 19, 2024 · Herein, we report a chemodivergent transformation of simple amides including primary, secondary, and tertiary amides using 1,1-diborylalkanes to access … nursing informatics and cyber security